碳回收

我们的分析测量技术应用范围从工业过程的二氧化碳和其他气体监测到用于化学品和合成燃料生产的催化剂材料分析，为碳回收技术的改进和推广做出了贡献。

碳回收是一种将二氧化碳 和废塑料有效转化为化学品、燃料、各种材料和热能的技术 。

碳回收技术的典型应用之一是甲烷化。它利用可再生能源使CO₂与H₂反应来合成甲烷(CH₄)。另一种是人工光合成技术，它像植物一样利用太阳能，以二氧化碳 为原料，将水和二氧化碳 转化为H₂和有机化合物。

内容列表

• 合成燃料和甲烷化
  • 气体浓度测量
  • Co-Electrolysis 电解评价
• CO₂衍生的化学品生产和人工光合成技术
  • 人工光合成技术光催化剂的衍生
• 混凝土材料的吸收和固定
• 材料回收
  • 纳米纤维素（CNF）的应用
• 化学品回收（拆解后在座位化学品和原材料使用）
• 热回收（焚烧并作为热能再利用）
• 工程支持

CO₂ Recycling (Utilization of Recovered CO₂)

Typical CO₂ recycling includes “synthetic fuel,” which is produced by reacting hydrogen produced by electrolyzing water with recovered CO₂ using renewable energy, methane (CH₄) production called “methanation,” production of chemicals using CO₂ as raw material, and production of hydrogen and organic compounds by “artificial photosynthesis” combining sunlight, water, and CO₂. photosynthesis, which combines sunlight, water, and CO₂ to produce hydrogen and organic compounds.

For more information on CO₂ capture technologies, please click here.

合成燃料是由二氧化碳 和氢合成而成的，用绿氢(利用可再生能源生产，且生产过程中无二氧化碳排放的氢)制成的燃料被称为“e燃料” 。

此外，甲烷化技术有望投入实际应用。它利用可再生能源产生的电力将水电解成氢和氧后，通过氢和二氧化碳的化学反应合成甲烷(CH₄)；或者可由水和二氧化碳共同电解得到的合成气(氢和一氧化碳的混合气)合成甲烷。甲烷可以作为液化天然气(LNG)的原料可用于城市燃气和制造甲醇，以这种方式生产的甲烷也称为“合成甲烷”或“碳中和甲烷”。

Synthetic fuel production is built around two main processes. One process produces synthesis gas (H₂ and CO) from CO₂ and hydrogen or water, and the other process produces synthetic fuel products from the produced synthesis gas.

Syngas Production　

Syngas (hydrogen and CO) production technologies include “reverse shift reaction,” which converts CO₂ to CO, “water electrolysis,” which breaks down water into hydrogen and oxygen by electrical force (electrolysis), and “co-electrolysis,” which simultaneously electrolyzes CO₂ and water. In order to put these technologies to practical use and optimize them, various research and development efforts are underway to optimize the production ratio of H₂ and CO, improve production energy efficiency, lower production costs including equipment, and improve durability. In “methanation,” where methane is produced by synthesizing water-electrolyzed hydrogen and CO₂, practical application, and optimization of the methanation process using co-electrolysis, which has less heat loss due to waste heat compared to the Sabatier reaction, is also being promoted. For example, in the research and development of co-electrolysis using Solid Oxide Electrolysis Cells (SOECs), it is important to evaluate SOECs under various environmental and test conditions in order to efficiently produce hydrogen and CO. In addition, to optimize the Sabatier reaction in methanation, it is essential to improve the yield of synthesis methane and the durability of the catalyst used.

HORIBA contributes to solving customers' problems with a variety of analytical, measurement, testing and evaluation solutions from research and development to commercialization of synthesis gas (H₂ and CO) production and methanation. Methanation requires measurement and monitoring of the concentrations of high concentrations of hydrogen and CO₂ as raw materials and of the synthesized methane gas. The Evaluator EC / ES water electrolysis cell stack evaluation system flows various gases to evaluate the hydrogen production performance and durability of SOECs.

HORIBA Solutions >>

R&D Applications

For High-Speed Simultaneous Measurement of Multi-Component Gases: FTIR Method Exhaust Gas Analyzer FTX-ONE Series
For measurement of a wide variety of trace gas components generated: Multi-Component Gas Analyzer VA-5000 series

Manufacturing Applications

For measurement of major gas components：Explosion-proof process gas analyzer 51 series

气体浓度监测

在甲烷化过程中，需要对作为甲烷化原料的高纯度氢气、CO₂以及合成甲烷气体的浓度进行测量和监测。

HORIBA 解决方案 >>

R&D 应用
用于测量多种生成的痕量气体： FTIR 排放分析仪 FTX-ONE 系列
用于测量主要气体成分： 多组分气体分析仪 VA-5000 系列

生产过程应用
用于测量主要气体成分： 多组分气体分析仪 VA-5000 系列
用于测量氢气浓度： 防爆型热导式氢气分析仪 TCA-51 系列
监测 CO₂ 和 CH₄ 浓度： 防爆红外分析仪 EIA-51d/p

联合电解测评

主要的甲烷化技术包括“Sabatier反应技术”，即通过电解水产生的氢气在Sabatier反应器中与CO2反应生成甲烷，以及“联合电解技术”，即水和CO2同时电解生成氢气和CO，随后在甲烷化反应器中用于生成甲烷。
与Sabatier反应技术相比，联合电解技术的能量转换效率更高，因为它在反应过程中产生的废热损失更少。

HORIBA 解决方案 >>

电解槽测试系统 Evaluator EC / ES 通过测量不同气体产品来评估SOEC的产氢性能和耐久性测试功率可从1W到100kW，温度范围可达1100°C。

CO₂-衍生化学生产和人工光合作用

以二氧化碳为原料，通过化学反应生产化学品和可储存能源(氢、甲醇、甲烷等)的技术，是碳循环利用的重要组成部分。其中利用太阳能从水和二氧化碳中合成烯烃等化学物质的技术，被称为“人工光合作用”，因为它类似于植物利用阳光和二氧化碳进行光合作用的机制。更高效的光催化剂的研发正在进行中，目的是实现一个脱碳的社会。

人工光合作用中光催化剂表征

为了有效地利用太阳光，需要将复杂的催化剂激发到长波长区域，如近红外区域。配合物催化剂的激发态与荧光光谱息息相关。

HORIBA 解决方案 >>

Duetta 荧光及吸收光谱仪可以评估近红外区域的发光特性，例如1000 nm以上，有助于提高催化剂材料的反应效率。

通过将吸收和固定混凝土中二氧化碳的“二氧化碳固定”与利用工业副产品相结合，可以减少混凝土生产(特别是水泥生产)中的二氧化碳排放总量。

HORIBA 解决方案 >>

EMIA-Step 碳/硫分析仪 可以在提高温度的同时测量碳的量，从而可以测量混凝土和其他材料吸附的 CO₂ 量随温度的变化。

The production lines and processes of conventional refineries (petroleum refineries) can also be utilized in the fuel production process using biomass. HORIBA provides products, engineering, and services based on its expertise in analytical and measurement technologies in petroleum refining, which it has cultivated over many years in the United States and contributes to the production of liquid fuels for mobility. When new fuels such as biofuels are actually used for mobility, it is important to conduct a comprehensive evaluation of the performance and durability of the mobility itself.

HORIBA Solution >>

Measurement Solutions for Petroleum Refining Processes
Evaluation Systems for Vehicles and Engines

Biomass and Biogas Power Generation

Biomass power generation can be achieved through direct combustion of biomass, pyrolysis of biomass at high temperatures to generate pyrolysis gas, and fermentation of biogas. HORIBA offers a broad lineup of analysis and measurement solutions, including equipment to improve power generation efficiency and to operate and manage exhaust gas treatment equipment, as well as continuous analysis equipment for special gases such as siloxane contained in biogas, thereby helping to solve issues related to biomass power generation.

Biomass Power Generation

Biogas Power Generation

HORIBA Solution >>

More detailed measurement solutions for biomass and biogas power generation

When energy is recovered as heat by burning non-recyclable biomass materials at waste disposal sites or waste incineration plants, the same issues that arise in power generation using plastic waste as fuel in thermal recovery may arise. For more information, please click here: Analysis and Measurement Solutions for Waste Power Generation

New Material (Cellulose Nanofiber)

 Cellulose nanofiber (CNF), which is made from wood and plant-derived biomass, is a new material that is one-fifth as light as steel but five times stronger. It is expected to be utilized in various foundational materials. For quality control and utilization of CNF, it is necessary to grasp the size of the fibers and the dispersion state in liquids (gels) at high speed and high resolution. HORIBA proposes a particle evaluation system that enables the evaluation of material properties at the nano-level.

HORIBA Solutions >>

For Particle Size Distribution Measurement of CNF: Centrifugal Nano Particle Analyzer Partica CENTRIFUGE
For structural evaluation of CNF gel materials: nanoPartica SZ-100V2

Material Recycling

In material recycling, waste plastics are used as raw materials to make new products. In the process of waste plastic sorting and reprocessing, it is important to determine the type of plastic used as raw material.
HORIBA provides solutions to determine the type of plastic by using new analysis and measurement methods.

HORIBA Solution >>

Non-contact automatic plastic identification: Hyperspectral camera and imaging systems

RPF(废纸和塑料燃料)是一种主要由废纸和废塑料制成的固化燃料。

RPF中氯浓度筛选分析

RPF可能含有氯(CI)，这是导致焚烧炉退化的原因之一，在使用RPF作为焚烧炉燃料之前检查氯(CI)有助于防止焚烧炉退化。

HORIBA 解决方案 >>

MESA-50 X射线荧光光谱仪是一款便携式，A4大小的台式x射线荧光分析仪，使用不需要液氮的SDD探测器，使元素分析简单快速。

Hydrogen and Syngas from Gasification

Various synthesis gases including hydrogen can be produced by gasification using plastic waste as the main raw material. The methane (CH₄) and hydrogen in these synthesis gases are used as raw materials for fuels and chemicals. 

Reductant for Blast Furnaces and Raw Material for Coke Ovens

The use of plastic waste as a reductant for blast furnaces and raw material for coke ovens reduces the number of resources needed for steelmaking. Continuous gas measurement of gases generated in blast furnaces and coke ovens helps to understand the impact of using plastic waste.

HORIBA Solutions >>

Solutions for the steel industry are summarized here. Please take a look.

气体和粉尘测量对以废塑料为燃料的焚烧厂和发电设施的运行优化和高效发电中起着重要的作用。

我们正在继续开发新的测量方法和解决方案。

HORIBA 解决方案>>

用于锅炉燃烧后烟气成分的准确和连续测量: 烟气监测系统ENDA-640ZG
用于氯化氢脱除过程和烟气监测：可调谐激光气体分析仪 TX-100
各种场合的温室气体测量，例如实验室：便携式气体分析仪 PG-300 系列
自动测量燃烧废气和空气中所含粉尘(微粒、烟尘、灰等)的质量浓度和元素组成: 自动颗粒物成分分析装置 PX-375

Solid Fuel (RPF)

RPF (Refuse Paper and Plastic Fuel) is a solid fuel made mainly from wastepaper and plastic, which is also used as fuel for power generation and gasification of plastic waste.

Screening analysis of chlorine content in RPF

RPF may contain chlorine (Cl), which is one of the causes of incinerator degradation. before using RPF as fuel for incinerators, chlorine content can be checked and removed to prevent incinerator degradation.

HORIBA Solution >>

For screening analysis of chlorine content in RPF: Desktop X-ray Fluorescence Analyzer MESA-50

Cement Manufacturing (Firing Process)

In the calcination process of cement production, plastic waste and biomass are used as fuel for temporary combustion furnaces that generate heat for pre-heaters and for rotary kilns. Some plants also combine methanation facilities that use CO₂ emitted from the calcination process as a raw material. HORIBA offers a wide lineup of analyzers, including continuous gas analyzers, which are necessary for improving productivity and operating and managing waste gas treatment equipment, thereby helping to solve problems in cement production.

Carbon Resource Circulation and Catalysts

To establish carbon resource recycling, it is necessary to accelerate and expand CO₂ recycling, biomass recycling, and plastic waste recycling. Common issues in carbon resource recycling include reducing manufacturing costs and improving the quality of the final product. In particular, improving the performance, cost, and durability of catalysts used in various manufacturing processes is directly related to solving these issues. Thus, carbon resource recycling and catalysts are closely related, and catalysts are evaluated and improved in each phase of catalyst R&D, demonstration of each process, social implementation, and product manufacturing at plants and other facilities. Specifically, it is important to ensure the quality of carbon resources, stable process operation, and elimination of impurities to prevent performance degradation and deterioration due to catalyst carbonization and poisoning.

HORIBA supports the R&D of catalysts for carbon recycling to the manufacturing of final products using catalyst-based processes with a variety of analytical, measurement, testing and evaluation solutions.

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